The word(s) "awwalu" appears 4 time(s) in 4 verse(s) in Quran.

(1) La shareeka lahu wabithalika omirtu waana awwalu almuslimeena

(سورة الأنعام, Al-An'aam, Chapter #6, Verse #163)
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(2) Walamma jaa moosa limeeqatina wakallamahu rabbuhu qala rabbi arinee anthur ilayka qala lan taranee walakini onthur ila aljabali faini istaqarra makanahu fasawfa taranee falamma tajalla rabbuhu liljabali jaAAalahu dakkan wakharra moosa saAAiqan falamma afaqa qala subhanaka tubtu ilayka waana awwalu almumineena

(سورة الأعراف, Al-A'raaf, Chapter #7, Verse #143)
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(3) Qul in kana lilrrahmani waladun faana awwalu alAAabideena

(سورة الزخرف, Az-Zukhruf, Chapter #43, Verse #81)
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(4) Huwa alawwalu waalakhiru waalththahiru waalbatinu wahuwa bikulli shayin AAaleemun

(سورة الحديد, Al-Hadid, Chapter #57, Verse #3)
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